By Pedro J. Pérez (Ed.),Pedro J. Pérez
Over the earlier decade, a lot examine attempt has been dedicated to the layout and synthesis of recent reagents and catalysts which may impression carbon-hydrogen bond activation, regularly a result of prospect that C−H activation may permit the conversion of inexpensive and plentiful alkanes into invaluable functionalized natural compounds.
Alkane C-H Activation through Single-Site steel Catalysis offers the present cutting-edge improvement within the catalytic platforms for the catalytic trans-formations of alkanes lower than homogeneous stipulations. bankruptcy 1 bargains a accomplished precis of the most discoveries discovered to this point. bankruptcy 2 stories the so-called electrophilic activation, initiated by way of Shulpín within the overdue 60s, and the bottom for the Catalytica system. bankruptcy three examines the catalytic borylation of alkanes, found through Hartwig, while bankruptcy four offers an up to date imaginative and prescient of the alkane dehydrogenation response. bankruptcy five covers the oxygenation of C-H bonds, a box of huge curiosity with bioinorganic im-plications, and at last bankruptcy 6 provides the functionalization of alkane C-H bonds by way of carbene or nitrene insertion.
The historical past of C-H bond activation, and the present study defined during this ebook, spotlight the present learn and current the reader with an outlook of this box which is still explored by means of an more and more visionary and enthusiastic crew of natural, organometallic, organic and actual chemists.
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Alkane C-H Activation by Single-Site Metal Catalysis: 38 (Catalysis by Metal Complexes) by Pedro J. Pérez (Ed.),Pedro J. Pérez